Ru(η5-indenyl)[(P(t-Bu)(Ph)](PPh3) | 1304789-41-0

• 英文名称: Ru(η5-indenyl)[(P(t-Bu)(Ph)](PPh3)
• CAS: 1304789-41-0
• 化学式: C₃₇H₃₆P₂Ru
• 分子量: 643.71
• InChiKey: KASBEHGEQMTIGP-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  Ru(η5-indenyl)[(P(t-Bu)(Ph)](PPh3) 、 碘甲烷 生成 RuI(η5-indenyl)[(P(t-Bu)(Ph)Me](PPh3)
  参考文献：
  名称：

  Diastereoselective synthesis of a “chiral-at-Ru” secondary phosphine complex

  摘要：

  Synthesis of the half-sandwich ruthenium complex [RuCl(eta(5)-indenyl){P(Bu(t))(Ph)H}(PPh(3))], 2, containing an unsymmetrically-substituted secondary phosphine, is described. A 60:40 kinetic distribution of the resulting diastereomers 2a and 2b shifts in solution at room temperature to give predominantly 2a. The relative stereochemistries at ruthenium and the secondary phosphine in each diastereomer have been assigned based on (1)H NOESY NMR and crystallographic data. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.12.058
• 作为产物：
  描述：

  RuCl(η5-indenyl)[(P(t-Bu)(Ph)H](PPh3)*0.33CH2Cl2 在 t-BuOK 作用下， 以 甲苯 为溶剂， 生成 Ru(η5-indenyl)[(P(t-Bu)(Ph)](PPh3)
  参考文献：
  名称：

  Diastereoselective synthesis of a “chiral-at-Ru” secondary phosphine complex

  摘要：

  Synthesis of the half-sandwich ruthenium complex [RuCl(eta(5)-indenyl){P(Bu(t))(Ph)H}(PPh(3))], 2, containing an unsymmetrically-substituted secondary phosphine, is described. A 60:40 kinetic distribution of the resulting diastereomers 2a and 2b shifts in solution at room temperature to give predominantly 2a. The relative stereochemistries at ruthenium and the secondary phosphine in each diastereomer have been assigned based on (1)H NOESY NMR and crystallographic data. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.12.058