[Cu2Cl4(N,N'-di(6-methyl-2-pyridyl)formamidine)2] | 587839-76-7

• 英文名称: [Cu2Cl4(N,N'-di(6-methyl-2-pyridyl)formamidine)2]
• CAS: 587839-76-7
• 化学式: C₂₆H₂₈Cl₄Cu₂N₈
• 分子量: 721.466
• InChiKey: YYSAPXRRCAGPIA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 N,N'-di(6-methyl-2-pyridyl)formamidine 以 二氯甲烷 为溶剂， 以17%的产率得到[Cu2Cl4(N,N'-di(6-methyl-2-pyridyl)formamidine)2]
  参考文献：
  名称：

  Structural characterization of copper complexes containing N,N′-di(6-methyl-2-pyridyl)formamidine

  摘要：

  The reactions of N,N'-di(6-methyl-2-pyridyl)formamidine (HDMepyF) with copper halide produced complexes of the types CuCl2(HDMepyF) (1), Cu2X4(HDMepyF)(2) (X = Cl, 2; X = Br 3), Cu4I4(HDMepyF)(2) (4), and [Cu,(HDMepyF)(2)](PF6)(2) (5). All complexes were characterized by X-ray crystallography. The structure of I is tetrahedral with the Cu(II) center chelated by one HDMepyF ligand and coordinated by two chloride ligands. Complexes 2 and 3 are dinuclear complexes, in which the two Cu(II) centers are bridged by two halide atoms. Each Cu(II) metal center are also coordinated by one terminal halide atom and chelated by one HDMepyF ligand, forming a distorted square-pyramidal geometry. Complex 4 is tetranuclear with the four copper atoms forming a parallelogram and each Cu atom being in a three-coordination environment. One iodo atom and one HDMepyF ligand bridge two adjacent copper atoms. In complexes 1-4, the neutral HDMepyF ligands coordinate to the metal centers through one amine nitrogen atom and one adjacent pyridine nitrogen atom. In dinuclear complex 5, the HDMepyF ligands coordinate to the Cu(I) ions in a tridentate fashion, forming a chelating and a bridging bonding modes. The molecules of 5 are chiral due to the ligand constraints and each Cu atom forms a trigonal-planar geometry. All the HDMepyF ligands in complexes 1-5 adopt the s-cis, s-trans conformation. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01478-0