(η5-C5Me5)Ir(η1(O):η3(C,C,O)-(R)-(C10H5(Br)O)2) | 1085525-74-1

• 英文名称: (η5-C5Me5)Ir(η1(O):η3(C,C,O)-(R)-(C10H5(Br)O)2)
• CAS: 1085525-74-1
• 化学式: C₃₀H₂₅Br₂IrO₂
• 分子量: 769.555
• InChiKey: QMRLGGOKSLBLHI-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 、 (R)-3,3'-dibromo-1,1'-bi-2-naphthol 在 Cs₂CO₃ 作用下， 以 二氯甲烷 为溶剂， 生成 (η5-C5Me5)Ir(η1(O):η3(C,C,O)-(R)-(C10H5(Br)O)2)
  参考文献：
  名称：

  A Rare η³ Binding Mode of Aryloxides in Iridium, Rhodium, and Ruthenium Complexes

  摘要：

  A rare eta(3) binding mode of aryloxides was obtained in the reaction of BINOL and [Cp*IrCl2](2). Interconversions between and eta(1) and eta(3) modes of aryloxides were observed by VT NMR spectroscopy, and the activation barrier was measured. The preference of this binding mode as a function of phenols was discussed.

  DOI：

  10.1021/om800985u