| 419543-28-5

• CAS: 419543-28-5
• 化学式: C₁₉H₂₁ClFeNO₃PPd
• 分子量: 540.074
• InChiKey: UBTHIWCSUKCKDA-LZNJKRCPSA-M

反应信息

• 作为产物：
  描述：

  吡啶 、 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Hydroxyferrocene as a prochiral analog of phenols: cyclopalladation of a mixed phosphite ester of hydroxyferrocene

  摘要：

  Hydroxyferrocene (ferrocenol), a metallocene analog of phenol, has been converted into a phosphite ester with chiral (racemic) butane-1,3-diol which undergoes cyclopalladation similarly to hydroxyarene phosphites. In this case, a planar chirality emerges but no diastereoselectivity has been observed. The molecular structure of the cyclopalladated product as pyridine add-act has been established by the X-ray study of a single crystal. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01228-1