| 586364-15-0

• CAS: 586364-15-0
• 化学式: C₄₀H₅₂Cl₈N₁₀Pd₄
• 分子量: 1382.22
• InChiKey: UHNOSKYUFOWFKW-VEFCNBLESA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 N,N,N',N'-Tetrakis-(3-{[1-pyridin-2-yl-meth-(E)-ylidene]-amino}-propyl)-butane-1,4-diamine 以 二氯甲烷 为溶剂， 以93%的产率得到
  参考文献：
  名称：

  The synthesis and catalytic activity of a first-generation poly(propylene imine) pyridylimine palladium metallodendrimer

  摘要：

  The preparation of a new palladium metallodendrimer is described. The first generation poly(propylene imine) dendrimer [DAB(NH2)(4)] has been modified by the reaction of the amino end groups with 2-pyridinecarboxaldehyde. Complexation reactions with PdCl2(COD) give rise to a metal-containing dendrimer with PdCl2 moieties bound on the periphery. The new metallodendrimer was used as a catalyst precursor, activated by methylaluminoxane (MAO), for the polymerization of ethylene. High molecular weight, high density polyethylene was obtained. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00173-6