ferrocenylketoacetaldehydate sodium | 1160714-04-4

• 英文名称: ferrocenylketoacetaldehydate sodium
• CAS: 1160714-04-4
• 化学式: C₁₃H₁₁FeO₂*Na
• 分子量: 278.066
• InChiKey: HWSJSYCYIHXVHG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  p-aminophenyl p-dodecyloxybenzoate 、 ferrocenylketoacetaldehydate sodium 在 盐酸 作用下， 以 乙醇 为溶剂， 以25%的产率得到1-ferrocenyl-1-([4-(4-dodecyloxybenzoyloxy)phenyl]amino)propen-2-one
  参考文献：
  名称：

  Synthesis and liquid crystal properties of copper(II) and palladium(II) chelates with new ferrocene-containing enaminoketones

  摘要：

  Heterometallic liquid crystals are of special interest because of the possibility to combine optical, magnetic and electric properties of different metal ions in one mesogenic molecule. In order to investigate new heteropolynuclear mesogenic systems, a series of beta-aminovinylketone ligands derived from acetyl ferrocene have been synthesized. Subsequently Cu(II) and Pd(II) ions were incorporated into the enaminoketone chelate core. The obtained ligands and complexes were characterized by element analysis, H-1 NMR, IR and UV-Vis spectroscopies. According to thermal polarizing microscopy and DSC studies, the ligands and Cu(II) complexes exhibit disordered soft crystal phases upon cooling from the isotropic liquid state. The Pd(II) complexes showed monotropic smectic C mesomorphism. The metal centres in the synthesized heteropolynuclear mesogens are in close vicinity to each other, which is of considerable interest from the viewpoint of the potential electron-transfer interactions between a ferrocene core and the central ions. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.01.045
• 作为产物：
  描述：

  乙酰基二茂铁 、 sodium 、 甲酸乙酯 以 苯 为溶剂， 以86%的产率得到ferrocenylketoacetaldehydate sodium
  参考文献：
  名称：

  Synthesis and liquid crystal properties of copper(II) and palladium(II) chelates with new ferrocene-containing enaminoketones

  摘要：

  Heterometallic liquid crystals are of special interest because of the possibility to combine optical, magnetic and electric properties of different metal ions in one mesogenic molecule. In order to investigate new heteropolynuclear mesogenic systems, a series of beta-aminovinylketone ligands derived from acetyl ferrocene have been synthesized. Subsequently Cu(II) and Pd(II) ions were incorporated into the enaminoketone chelate core. The obtained ligands and complexes were characterized by element analysis, H-1 NMR, IR and UV-Vis spectroscopies. According to thermal polarizing microscopy and DSC studies, the ligands and Cu(II) complexes exhibit disordered soft crystal phases upon cooling from the isotropic liquid state. The Pd(II) complexes showed monotropic smectic C mesomorphism. The metal centres in the synthesized heteropolynuclear mesogens are in close vicinity to each other, which is of considerable interest from the viewpoint of the potential electron-transfer interactions between a ferrocene core and the central ions. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.01.045