| 942608-91-5

• CAS: 942608-91-5
• 化学式: C₁₅H₂₀FeSi
• 分子量: 284.256
• InChiKey: PPEQXQQRBQUEAK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  trimethyl((1R)-1-[(1R)-1-(trimethylsilyl)ferrocen-2-yl]ethyl)ammonium iodide 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Structure of an Enantiomerically Pure C2 Symmetric Ferrocenyl Carbene

  摘要：

  The straightforward, high-yield synthesis and X-ray structural analysis of the air-stable planar-chiral bis(ferrocenyl)carbene 1,3-bis-{(1R)-1-[(IR)-1-(trimethylsilyl)ferrocen-2-yl]ethyl}imidazol-2-ylidene (5) is reported. Compound 5 is obtained in four steps from the amine [(1R)-1-(dimethylamino)ethyl]ferrocene (1) upon diastereoselective silylation, methylation, nucleophilic substitution by imidazole, and deprotonation. The X-ray crystal structure of the free carbene shows the typical conformational features of the 1,2-disubstituted ferrocenyl units, as found in other ferrocenyl ligands derived from 1.

  DOI：

  10.1002/1522-2675(200208)85:8<2518::aid-hlca2518>3.0.co;2-n