fac-Re(5-aza-18-crown-6-1,10-phenanthroline)(CO)3Cl | 169232-76-2

• 英文名称: fac-Re(5-aza-18-crown-6-1,10-phenanthroline)(CO)3Cl
• CAS: 169232-76-2
• 化学式: C₂₇H₃₁ClN₃O₈Re
• 分子量: 747.218
• InChiKey: BHMNSTMNUFULDN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  五羰基氯铼(I) 、 5-(aza-18-crown-6)-1,10-phenanthroline 以 甲苯 为溶剂， 以86%的产率得到fac-Re(5-aza-18-crown-6-1,10-phenanthroline)(CO)3Cl
  参考文献：
  名称：

  A Versatile Preparative Route to 5-Substituted-1,10-Phenanthroline Ligands via 1,10-Phenanthroline 5,6-Epoxide

  摘要：

  The reactive ligand 1,10-phenanthroline-5,6-epoxide is a versatile starting material for the preparation of a variety of 5-substituted-1, 10-phenanthroline ligands by reaction with oxygen-, carbon-, or nitrogen-based nucleophiles. All of the new ligands readily form complexes with the fac-Re-1(CO)(3)Cl fragment. Of particular interest are the syntheses of the amino and aminocrown derivatives of Re-1 which can function as cation sensors by perturbation of molecular luminescence. An interesting example involving Pb2+ is presented.

  DOI：

  10.1021/ic00129a003