Ni(N,N'-bis(4-methoxylbenzyl)-diethylenetriamine)(phenanthroline)Cl(ClO4) | 872467-20-4

• 英文名称: Ni(N,N'-bis(4-methoxylbenzyl)-diethylenetriamine)(phenanthroline)Cl(ClO4)
• CAS: 872467-20-4
• 化学式: C₃₂H₃₇ClN₅NiO₂*ClO₄
• 分子量: 717.272
• InChiKey: PCUXCJJMLUBHKH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 nickel(II) perchlorate hexahydrate 、 1,7-bis(4-methoxybenzyl)diethylenetriamine tris hydrochloride 在 NaOH 作用下， 以 甲醇 为溶剂， 以41.8%的产率得到Ni(N,N'-bis(4-methoxylbenzyl)-diethylenetriamine)(phenanthroline)Cl(ClO4)
  参考文献：
  名称：

  Synthesis and 1-D Double Line Supramolecular Structure of a Ni(II) Complex with N-alkylated Dien

  摘要：

  A novel N-alkylated diethylenetriamine ligand L center dot 3HCl (L=N, N'-bis(4-methoxylbenzyl)-diethylenetriamine) and its mononuclear Ni(II) complex [Ni(L) phenCl] ClO4 (1) ( phen = o-phenanthroline) were synthesized and spectroscopically characterized. X-ray analysis indicates that octahedral geometry of the Ni( II) center is finished by three N atoms of dien moiety of the ligand in meridional fashion, two N atoms of phen and one Cl anion. Along the a axis, the neighboring molecules are connected via hydrogen bonds involving ClO4- anions and N-H groups of the ligands, thus forming a 1-D linear structure which is further connected to the other symmetry-related line via pi center dot center dot center dot pi stacking interactions of phen rings. The steric effect related to the molecular structure of L has been discussed.

  DOI：

  10.1081/sim-200066988