| 157312-88-4

• CAS: 157312-88-4
• 化学式: C₃₈H₃₅NO₂PRh
• 分子量: 671.581
• InChiKey: HKYALSQEJBJENI-JMUAPCIWSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三对苯甲基膦 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Reactivity of [Rh(quin)(NBD)] towards arylic mono- and diphosphine ligandsVI

  摘要：

  NBD ligand (NBD = 2,5-norbornadiene, bicyclo[2,2,1]hepta-2,5-diene) was easily displaced from [Rh(quin)(NBD)] (quin = 2-quinaldinate, C9H6NCOO-) by PR3 phosphine ligands [R = (4-X-C6H4)3, X = CH3O, CH3, F, Cl] to produce the disubstituted [Rh(quin)(PR3)2] complexes. These reactions occur through a penta-coordinate intermediate, [Rh(quin)(NBD)(PR3)], whose stability in solution suggests an associative mechanism when PR3 = P(4-CH3OC6H4)3, P(4-CH3C6H4)3 and an interchange mechanism when PR3 = P(4-F-C6H4)3, P(4-ClC6H4)3. Reactions of [Rh(quin)(NBD)] with diphosphine ligands, dppe [1,2-bis(diphenylphosphino)ethane] or dppm [bis(diphenylphosphino) methane], gave rise to the [Rh(quin)(P-P)] complexes (P-P = dppe, dppm) which had been previously prepared from [Rh(quin)(CO)2]. A binuclear intermediate [{Rh(quin)(NBD)}2(mu-P-P)] has been isolated in the above reactions. Comparison between the behaviour of [Rh(quin)(CO)2] and [Rh(quin)(NBD)] towards PR3 or P-P ligands is established. Conclusions related to the influence of leaving or substituent ligands to produce complexes of the type [Rh(quin)(P)2] [(P)2 = 2PR3, P-P] were deduced.

  DOI：

  10.1016/s0277-5387(00)83452-x
• 作为产物：
  描述：

  (2-quinaldinate)(bicyclo-2,2,1-hepta-2,5-diene)rhodium(I) 、 三对苯甲基膦 以 氯仿 为溶剂， 以80-90的产率得到
  参考文献：
  名称：

  Reactivity of [Rh(quin)(NBD)] towards arylic mono- and diphosphine ligandsVI

  摘要：

  NBD ligand (NBD = 2,5-norbornadiene, bicyclo[2,2,1]hepta-2,5-diene) was easily displaced from [Rh(quin)(NBD)] (quin = 2-quinaldinate, C9H6NCOO-) by PR3 phosphine ligands [R = (4-X-C6H4)3, X = CH3O, CH3, F, Cl] to produce the disubstituted [Rh(quin)(PR3)2] complexes. These reactions occur through a penta-coordinate intermediate, [Rh(quin)(NBD)(PR3)], whose stability in solution suggests an associative mechanism when PR3 = P(4-CH3OC6H4)3, P(4-CH3C6H4)3 and an interchange mechanism when PR3 = P(4-F-C6H4)3, P(4-ClC6H4)3. Reactions of [Rh(quin)(NBD)] with diphosphine ligands, dppe [1,2-bis(diphenylphosphino)ethane] or dppm [bis(diphenylphosphino) methane], gave rise to the [Rh(quin)(P-P)] complexes (P-P = dppe, dppm) which had been previously prepared from [Rh(quin)(CO)2]. A binuclear intermediate [{Rh(quin)(NBD)}2(mu-P-P)] has been isolated in the above reactions. Comparison between the behaviour of [Rh(quin)(CO)2] and [Rh(quin)(NBD)] towards PR3 or P-P ligands is established. Conclusions related to the influence of leaving or substituent ligands to produce complexes of the type [Rh(quin)(P)2] [(P)2 = 2PR3, P-P] were deduced.

  DOI：

  10.1016/s0277-5387(00)83452-x