| 172702-72-6

• CAS: 172702-72-6
• 化学式: C₄₀H₇₂Al₄O₁₆S₂
• 分子量: 981.06
• InChiKey: DWQZPBXLZDJIJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  硫二甘醇 、 以 苯 为溶剂， 以100%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of some unique heterocyclic derivatives containing aluminium(III) atoms in 4- and 6-coordination states—3. Reaction of bis(β-diketonato) aluminium(III)-di-μ-isopropoxo di-isopropoxo aluminium(III) with 2-mercaptoethanol and 2,2′-thiodiethanol

  摘要：

  Reactions of bis(beta-diketonato) aluminium (III)-di-mu-isopropoxo di-isopropoxo aluminium(III), [(beta-diketo)(2)Al(mu-OPri)(2)Al(OPri)(2)], with 2-mercaptoethanol, [HO(CH2)(2)SH], and 2,2'-thiodiethanol, [HO(CH2)(2)S(CH2)(2)OH], in 1:1 stoichiometry have resulted in the synthesis of [(beta-diketo)(2)Al(mu-OPri)(2)Al{O(CH2)(2)S}](n) and [(beta-diketo)(2)Al(mu-OPri)(2) Al{O(CH2)(2)S(CH2)(2)O}](n), respectively (where, 1 for ethylacetoacetato and n = 2 for acetylacetonato). These are soluble in common organic solvents. Suitable structures based on elemental analysis, molecular weight measurements, IR and NMR (H-1, C-13 and Al-27) spectral studies have been proposed. Al-27 spectra show the presence of both octahedrally and tetrahedrally coordinated aluminium sites.

  DOI：

  10.1016/0277-5387(95)00276-x