di-μ-trifluoroacetato-bis[dicarbonyl(pyridine)ruthenium(I)] | 671215-02-4

• 英文名称: di-μ-trifluoroacetato-bis[dicarbonyl(pyridine)ruthenium(I)]
• 英文别名: di-μ-trifluoroacetato-tetracarbonyldipyridinediruthenium(I)
• CAS: 671215-02-4
• 化学式: C₁₈H₁₀F₆N₂O₈Ru₂
• 分子量: 698.416
• InChiKey: TWXKPOFTBBYLPN-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  三氟乙酸 、 di-μ-O,O'-acetatotetracarbonylbis(pyridine)diruthenium(I) 以 三氟乙酸 为溶剂， 以12%的产率得到di-μ-trifluoroacetato-bis[dicarbonyl(pyridine)ruthenium(I)]
  参考文献：
  名称：

  Di-μ-benzoato-bis[dicarbonyl(pyridine)ruthenium(I)] (new polymorph) and di-μ-trifluoroacetato-bis[dicarbonyl(pyridine)ruthenium(I)]

  摘要：

  The syntheses and crystal structure determinations of a pair of 'sawhorse' dimers are reported, viz. [Ru-2(C6H5CO2)(2)(C5H5N)(2)(CO)(4)] [a new polymorph, cf. Kepert, Deacon, Spiccia, Fallon, Skelton & White (2000). J. Chem. Soc. Dalton Trans. pp. 2867-2874] and [Ru-2(CF3CO2)(2)(C5H5N)(2)(CO)(4)]. The Ru...Ru distances are 2.6724 (2) and 2.7122 (5) Angstrom, respectively.

  DOI：

  10.1107/s0108270103023709