1,2-bis(4-((2,2-difluoro-4,6-dimethyl-2H-1l3,3,2l4-dioxaborinin-5-yl)thio)-5-methyl-1,3-dithiol-2-ylidene)-1,2-diphenylethane | 1186011-35-7

• 英文名称: 1,2-bis(4-((2,2-difluoro-4,6-dimethyl-2H-1l3,3,2l4-dioxaborinin-5-yl)thio)-5-methyl-1,3-dithiol-2-ylidene)-1,2-diphenylethane
• CAS: 1186011-35-7
• 化学式: C₃₂H₂₈B₂F₄O₄S₆
• 分子量: 766.584
• InChiKey: YSVSIYDAFACBJY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3,3'-(((1,2-diphenylethane-1,2-diylidene)bis(5-methyl-1,3-dithiole-4-yl-2-ylidene))bis(sulfanediyl))bis(pentane-2,4-dione) 在 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以34%的产率得到1,2-bis(4-((2,2-difluoro-4,6-dimethyl-2H-1l3,3,2l4-dioxaborinin-5-yl)thio)-5-methyl-1,3-dithiol-2-ylidene)-1,2-diphenylethane
  参考文献：
  名称：

  Tetrathiafulvalenyl-acetylacetonate complexes of difluoroboron

  摘要：

  A series of tetrathiafulvalene (TTF) derivatives functionalized by one or two beta-diketonatoboron difluoride groups were synthesized through the addition of borontrifluoride to TTF Substituted by one or two acetylacetone functions. The influence of the beta-diketonatoboron difluoride moiety on the redox properties of the TTF has been investigated by cyclic voltammetry. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.05.041