catena-poly[[diaquadichloroiron(II)]-μ1,4-dioxane-κ2O:O'] | 45846-04-6

• 英文名称: catena-poly[[diaquadichloroiron(II)]-μ1,4-dioxane-κ2O:O']
• CAS: 45846-04-6
• 化学式: C₄H₁₂Cl₂FeO₄
• 分子量: 250.89
• InChiKey: RCAIFTXNJGENIV-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  1,4-二氧六环 、 iron(II) chloride 在 LiCl 作用下， 以 1,4-二氧六环 为溶剂， 生成 catena-poly[[diaquadichloroiron(II)]-μ1,4-dioxane-κ2O:O']
  参考文献：
  名称：

  catena-Poly[[diaquadichloroiron(II)]-μ-1,4-dioxane-κ²O:O′]

  摘要：

  The crystal structure of the title compound, [FeCl2 (C-4 H8O2)(H2O)(2)](n), contains six-coordinate Fe-II atoms in approximately octahedral environments. The Fe-II atoms have (1) over bar symmetry, i.e. all pairs of identical ligands are trans. The structure consists of polymeric chains made up of dioxane molecules, in the chair conformation with (1) over bar symmetry, linking the Fe-II centers. The chains are crosslinked by O-H...Cl hydrogen bonds.

  DOI：

  10.1107/s0108270102010508