(η5-cyclopentadienyl)bis(triphenylphosphine)(4-cyano-1,2,3-triazolato)osmium(II) | 1031858-79-3

• 英文名称: (η5-cyclopentadienyl)bis(triphenylphosphine)(4-cyano-1,2,3-triazolato)osmium(II)
• CAS: 1031858-79-3
• 化学式: C₄₄H₃₆N₄OsP₂
• 分子量: 872.944
• InChiKey: NSBARSCXKZCQFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (η5-cyclopentadienyl)bis(triphenylphosphine)(azide)osmium(II) 、 butenedinitrile 以 二氯甲烷 为溶剂， 以72.1%的产率得到(η5-cyclopentadienyl)bis(triphenylphosphine)(4-cyano-1,2,3-triazolato)osmium(II)
  参考文献：
  名称：

  Reactivity study of cyclopentadienyl osmium(II) bisphosphine azido complexes with activated alkynes and nitriles: Isolation of osmium triazolato and tetrazolato complexes by 1,3-dipolar addition

  摘要：

  The cyclopentadienyl osmium(II) complexes [(eta(5)-C5H5)Os(PPh3)(2)X] [X = Br (1), CH3CN (2)] reacts with sodium azide (NaN3) to yield the corresponding azido complex [(eta(5)-C5H5)Os(PPh3)(2)N-3] (3). This undergoes [3+2] dipolar cycloaddition reaction with activated alkynes like dimethyl and diethyl acetylenedicarboxylate to yield triazolato complexes [(eta(5)-C5H5)Os(PPh3)(2){N3C2(CO2R)(2)}] [R = -CH2CH3 (4) and -CH3 (5)]. The complex 3 also reacts with nitriles such as tetracyanoethylene (TCE), fumaronitrile and p-nitrobenzonitrile to yield complexes of the type [(eta(5)-C5H5)Os(PPh3)(2){N4C2(CN)=C(CN)(2)}] (6), [(eta(5)-C5H5)Os(PPh3)(2){N3C2HCN}] (7) and [(eta(5)-C5H5)Os(PPh3)(2){N4C(C6H4-p-NO2)}] (8). These complexes were fully characterized on the basis of microanalyses, FT-IR and NMR spectroscopic data. The molecular structure of the representative complex [(eta(5)-C5H5)Os(PPh3)(2){N3C2(CO2CH2CH3)(2)}] (4) was determined by single crystal X-ray analysis. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.10.016