(dibenzo[a,c]phenazin-7-ido)(dipyrido[a,c]phenazine)palladium(II) hexafluorophosphate | 952303-80-9

• 英文名称: (dibenzo[a,c]phenazin-7-ido)(dipyrido[a,c]phenazine)palladium(II) hexafluorophosphate
• 英文别名: [Pd(dbpz)(dppz)]PF6
• CAS: 952303-80-9
• 化学式: C₃₈H₂₁N₆Pd*F₆P
• 分子量: 813.009
• InChiKey: UYBOXEYSDALPEO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 二吡啶并[3,2-a:2',3'-c]吩嗪 、 PdCl2(dibenzo[a,c]phenazine) 以 甲醇 、 二氯甲烷 为溶剂， 以96%的产率得到(dibenzo[a,c]phenazin-7-ido)(dipyrido[a,c]phenazine)palladium(II) hexafluorophosphate
  参考文献：
  名称：

  Spectroscopic and electrochemical properties of cyclopalladated complexes based on dibenzo[a,c]phenazine

  摘要：

  Cyclopalladated complexes based on dibenzo[a,c]phenazine were studied by H-1 NMR and electronic absorption and emission spectroscopy, and cyclic voltammetry. Replacement of ethylenediamine by heterocyclic ligands scarcely affects the coordination-induced proton shifts of the diazine part of the cyclometalated ligand, but, as the basicity of chelated ligands decreases, the screening of protons of the carbanionic part of those cyclometalated ligands which is the most proximate to the coordination center regularly decreases. Cyclopalladation reveals itself in the following characteristic parameters of photo- and electro-induced electron-transfer processes: longwave absorption band, lambda(max) (437 +/- 7) nm and epsilon (3.0 +/- 1.5)x 10(3) l mol(-1) cm(-1), vibration-structured low-temperature luminescence resulting from spin-forbidden optical transition from the excited to ground state of the complex with the energy E-infinity (16.98 +/- 0.03) kK and the lifetime T (190 +/- 20) mu s, and reversible one-electron electroreduction wave with E-1/2 -(1.39 +/- 0.03) V.

  DOI：

  10.1134/s1070363206100240