[Pd(I)Br(μ-PhN(P(OC6H4OMe-o)2)2)]2 | 947259-29-2

• 英文名称: [Pd(I)Br(μ-PhN(P(OC6H4OMe-o)2)2)]2
• CAS: 947259-29-2
• 化学式: C₆₈H₆₆Br₂N₂O₁₆P₄Pd₂
• 分子量: 1663.82
• InChiKey: CQBVRAAWLATOIF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tris(dibenzylideneacetone)dipalladium(0) chloroform complex 、 PhN(P(OC6H4OMe-o)2)2 、 bis(acetonitrile)palladium(II) bromide 以 二氯甲烷 为溶剂， 以45%的产率得到[Pd(I)Br(μ-PhN(P(OC6H4OMe-o)2)2)]2
  参考文献：
  名称：

  Synthesis and structural studies of RhI, PdI, NiII complexes and one-pot synthesis of binuclear RuII complex [(η6-p-cymene)Ru(μ2-Cl)3Ru{PhN(P(OC6H4OMe-o)2)2}Cl]

  摘要：

  The Rh-I, Ru-II, Pd-I and Ni-II complexes of the aminobis(phosphonite), PhN(P(OC6H4OMe-o)(2))(2) (1) are reported. The reactions of 1 with [Rh(COD)Cl](2) in 1:1 and 2:1 molar ratio afford the mono- and diolefin substituted chloro bridged chelate complexes, [(COD)Rh-2(mu(2)-Cl)(2){PhN(P(OC6H4OMe-o)(2))(2)}] (2) and [Rh(mu(2)-Cl){PhN(P(OC6H4OMe-o)(2))(2)}](2) (3), respectively. Similarly, the cationic mono- and bis-chelate complexes, [Rh(COD)(PhN(P(OC6H4OMe-o)(2))(2)}]OTf (4) and [Rh{PhN(P(OC6H4OMe-o)(2))(2)}(2)]OTf (5) are obtained by treating 1 with [Rh(COD)Cl](2) in the presence of AgOTf in appropriate ratios. The dinuclear Rh-I carbonyl complex, [RhCl(CO){mu-PhN(P(OC6H4OMe-o)(2))(2)}](2) (6) is prepared by treating 1 with 0.5 equiv. of [Rh(CO)(2)Cl](2). Reaction of 1 with cis-[NiBr2(DME)] (DME = 1,2-dimethoxyethane) affords [{PhN(P(OC6H4OMe-o)(2))(2)} NiBr2] (7) whereas with [Ru-(eta(6)-p-cymene)Cl-2](2) in refluxing THF medium produces an interesting and rare bimetallic Ru-II complex, [(eta(6)-p-cymene)Ru(mu(2)-Cl)(3)Ru{PhN(P(OC6H4OMe-o)(2))(2))Cl] (8). Redox condensation of the Pd-0 and Pd-II derivatives with 1 affords the dinuclear Pd-I complex, [PdBr{mu-PhN(P(OC6H4OMe-o)(2))(2)}](2) (9). The formation and structure of complexes 2-9 are assigned through various spectroscopic and micro analysis data. The molecular structures of 5 and 7-9 are confirmed by single crystal X-ray diffraction studies. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.04.019