[chlororuthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)]chloride | 932368-67-7

• 英文名称: [chlororuthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)]chloride
• CAS: 932368-67-7
• 化学式: C₄₈H₃₉ClN₃P₂Ru*Cl
• 分子量: 891.781
• InChiKey: VNFJTXYMHGFEDN-BMKZIQKJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 [chlororuthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)]chloride 、 水 在 silver(I) 4-methylbenzenesulfonate 作用下， 以 乙醇 、 水 为溶剂， 以65%的产率得到[(aqua)ruthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)] hexafluorophosphate
  参考文献：
  名称：

  Effect of the cis- and trans-[1,2-bis(diphenylphosphino)ethylene] ligands in the properties of diphosphine–polypyridyl complexes of ruthenium(II)

  摘要：

  The ruthenium(II) complexes [Ru(cis-L)(totpy)(H2O)](PF6)(2) (1) and [Ru(trans-L)(2)(totpy)(H2O)](PF6)(2) (2) (L=1,2-bis(diphenylphosphino)ethylene; totpy = 4'-(4-tolyl)-2,2':6',2"-terpyridine) were synthesized and characterized by elemental analysis, cyclic and differential pulse voltammetries and UV-vis, IR and P-31 NMR spectra. The redox potentials of 2 are less anodic than those of 1. The redox potentials are a result of the different environments created by the phosphine ligands in the trans-complex, associated with their electron donating effect. Electrocatalytic oxidations of benzyl alcohol, cyclohexanol, 1-pentanol, 1,2-butanediol, 1,4-butanediol and cyclohexene, were performed using complexes I and 2 both in solution and immobilized in carbon paste electrode. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2006.05.059
• 作为产物：
  描述：

  [trichloro(4'-tolyl-2,2':6',2''-terpyridine)ruthenium(III)] 、 顺-1,2-双(二苯基膦)乙烯 在 三乙胺 、 lithium chloride 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 以80%的产率得到[chlororuthenium(II)(cis-1,2-bis(diphenylphosphino)ethylene)(4'-(4-tolyl)-2,2':6',2''-terpyridine)]chloride
  参考文献：
  名称：

  Effect of the cis- and trans-[1,2-bis(diphenylphosphino)ethylene] ligands in the properties of diphosphine–polypyridyl complexes of ruthenium(II)

  摘要：

  The ruthenium(II) complexes [Ru(cis-L)(totpy)(H2O)](PF6)(2) (1) and [Ru(trans-L)(2)(totpy)(H2O)](PF6)(2) (2) (L=1,2-bis(diphenylphosphino)ethylene; totpy = 4'-(4-tolyl)-2,2':6',2"-terpyridine) were synthesized and characterized by elemental analysis, cyclic and differential pulse voltammetries and UV-vis, IR and P-31 NMR spectra. The redox potentials of 2 are less anodic than those of 1. The redox potentials are a result of the different environments created by the phosphine ligands in the trans-complex, associated with their electron donating effect. Electrocatalytic oxidations of benzyl alcohol, cyclohexanol, 1-pentanol, 1,2-butanediol, 1,4-butanediol and cyclohexene, were performed using complexes I and 2 both in solution and immobilized in carbon paste electrode. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2006.05.059