2,3-二氰基吡嗪 、 氯化镥(III) 以
neat (no solvent) 为溶剂,
以31%的产率得到chloro(tetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III)
参考文献:
名称:
Synthesis and properties of lanthanide complexes with tetrapyrazinoporphyrazine and its substituted derivatives
摘要:
Reactions of dicyanopyrazine and its tert-butyl-, diphenyl-, and dipyridyl-substituted derivatives with erbium, thulium, ytterbium, and lutetium chlorides, acetates, and acetylacetonates gave the corresponding tetrapyrazinoporphyrazine metal complexes which were characterized by elemental analyses, and IR, H-1 NMR, and electronic absorption spectra. The stability of the complexes to thermooxidative decomposition in air was also studied.