Li[(C5H4CH3)(CO)2MnC(O)(C6H4-4-OCH3)] | 143887-80-3

• 英文名称: Li[(C5H4CH3)(CO)2MnC(O)(C6H4-4-OCH3)]
• CAS: 143887-80-3
• 化学式: C₁₆H₁₄MnO₄*Li
• 分子量: 332.164
• InChiKey: HFLNFVPTOKMDKL-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  Li[(C5H4CH3)(CO)2MnC(O)(C6H4-4-OCH3)]*diethyl ether 以 neat (no solvent) 为溶剂， 生成 Li[(C5H4CH3)(CO)2MnC(O)(C6H4-4-OCH3)]
  参考文献：
  名称：

  Manganese Trifluoroacetoxycarbene Complexes Are Convenient Intermediates in the Synthesis of Cyclic Enediynes

  摘要：

  Trifluoroacetoxycarbene complexes generated from reaction of stable manganese acyl complexes with trifluoroacetic anhydride are convenient alternatives to thermally sensitive manganese carbyne complexes in reactions with diynes that lead eventually to free cyclic enediynes. In situ reaction of these trifluoroacetoxycarbene complexes with alkynyl copper intermediates generated from diynes, CuBr, and NEt(i-Pr)(2) led to the isolation of cyclic enediynes via intermediate linked alkynylcarbene complexes and manganese enediyne complexes.

  DOI：

  10.1021/om030561+