| 188600-68-2

• CAS: 188600-68-2
• 化学式: C₄₄H₃₆Cl₄Co₂N₈
• 分子量: 936.622
• InChiKey: ATEDRWATCNXDOK-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 1,4-bis(benzimidazole-1-ylmethyl)benzene 以 甲醇 、 水 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Metal supported macrocycles: Synthesis and characterization of some new 1,3-bis(benzimidazol-1-yl-methylene)benzene and 1,4-bis(benzimidazol-1-yl-methylene)benzene-bridged metal(II) cation complexes

  摘要：

  Two new non-chelating bidentate ligands 1,3-bis(benzimidazol-1-yl-methylene)benzene, hereafter 1,3-BIX, and 1,4-bis[benzimidazol-1-yl-methylene]benzene, hereafter 1,4-BIX, have been synthesized and their complexes with M(II) salts (M = Co, Ni, Cu, Zn, Pd and Pt) have been prepared and characterized using elemental analysis, magnetic moment measurement, IR, UV-vis and C-13 NMR and FAB-MS (in some cases) studies. Cu-II, Pd-II and Pt-II metal ions yield dinuclear square-planar complexes viz. [enM(BIX)](2)X(4) (en = 1,2 diaminoethane; M = Pd or Pt, X = NO3; M = Cu, X = ClO4, BIX = 1,3- or 1,4-BIX). Co-II chloride forms dimeric tetrahedral [Co(BIX)Cl-2](2), whereas Ni-II and Zn-II chlorides yield polymeric [M(BIX)Cl-2](n) complexes. Copyright (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00407-x