| 194037-58-6

• CAS: 194037-58-6
• 化学式: CF₃O₃S*C₁₆H₂₀N₂S₃*F₆P*Pd
• 分子量: 737.001
• InChiKey: MNBMVECQGSXKIX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 silver trifluoromethanesulfonate 、 1,9-bis(2-pyridyl)-2,5,8-trithianonane 、 palladium dichloride 以 乙腈 为溶剂， 以47%的产率得到
  参考文献：
  名称：

  Complexes of cobalt, nickel, palladium and silver with N2Sx (x=3 or 4) ligands involving aromatic nitrogen and thioether donors

  摘要：

  Preparations of eleven complexes of the open-chain, aromatic nitrogen/thioether donor, N2S3 and N2S4 ligands, L1 and L2, are described. The complexes have been characterized by using conductivity, cyclic voltammetry, magnetic susceptibility, ESR, NMR and UV-Vis spectroscopies where appropriate and by X-ray crystallography for [Co(L2)][ClO4](2). Crystal data: monoclinic, space group C2/c, a=18.177(3), b=11.600(2), c=14.552(2) Angstrom, beta=124.703(6)degrees, Z=4, R=0.039, R-w=0.050. The presence of a spin-crossover system for the Co(II) complexes has been detected.

  DOI：

  10.1016/s0020-1693(96)05572-7