(4-diphenylphosphino)phenyl-2-N,N-dimethylaminomethylferrocene | 1427217-97-7

• 英文名称: (4-diphenylphosphino)phenyl-2-N,N-dimethylaminomethylferrocene
• CAS: 1427217-97-7
• 化学式: C₃₁H₃₀FeNP
• 分子量: 503.407
• InChiKey: RJDUALKWCBRPLW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (4-diphenylphosphino)phenyl-2-N,N-dimethylaminomethylferrocene 在 selenium 作用下， 反应 4.0h， 生成
  参考文献：
  名称：

  Aryl-based ferrocenyl phosphine ligands in the rhodium(I)-catalyzed hydroformylation of olefins

  摘要：

  Ferrocenyl-based phosphine ligands [Fe{1-PPh2(spacer)-2-NMe2CH2C5H3} (C5H5)] (spacer =1,4-phenylene (rac-1), 1,3-phenylene (rac-2), 4,4'-biphenylene (rac-3), 2,5-thienylene (rac-4)) were applied in the rhodium(I)-catalyzed hydroformylation of various olefins (styrene, allylbenzene and 1-hexene) with higher chemo- and regioselectivity than a rhodium(I) catalyst precursor alone. The different sigma-donor properties of rac-1-4 were elucidated by P-31{H-I} NMR spectroscopy of the corresponding selenides. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2013.11.027
• 作为产物：
  描述：

  1-(4-diphenylphosphine oxide)phenyl-2-N,N-dimethylaminomethylferrocene 在 三氯硅烷 、 三乙胺 作用下， 以 甲苯 为溶剂， 以96%的产率得到(4-diphenylphosphino)phenyl-2-N,N-dimethylaminomethylferrocene
  参考文献：
  名称：

  1,2-Disubstituted Aryl-Based Ferrocenyl Phosphines

  摘要：

  Ferrocenylaryl- or ferrocenylheteroarylphosphines [Fe{1-PPh2(spacer)-2-NMe2CH2C5H3}(C5H5)] (spacer = 1,4-phenylene (rac-6), 1,3-phenylene (rac-7), 4,4'-biphenylene (rac-8), 2,5-thienylene (rac-9)) were prepared in a facile two-step sequence starting with Negishi cross-coupling between N,N-dimethylaminomethylferrocene and aryl halide phosphine oxides, Br-spacer-P(O)Ph-2, by reduction with trichlorosilane. All products were characterized spectroscopically (H-1, C-13, and P-31 NMR, MS, FTIR), and rac-6, the corresponding phosphine oxide rac-2, and rac-9 were also characterized by X-ray crystallography. Furthermore, the redox properties of rac-2-9 were studied by cyclic voltammetry.

  DOI：

  10.1021/om400117n