Pd(C6H4(o-Ph)N(PPh2)2)Cl2 | 898232-83-2

• 英文名称: Pd(C6H4(o-Ph)N(PPh2)2)Cl2
• CAS: 898232-83-2
• 化学式: C₃₆H₂₉Cl₂NP₂Pd
• 分子量: 714.906
• InChiKey: PKQBKZQGDXAQJD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 Diphenylphosphanyl-diphenyl-(2-phenylphenyl)imino-lambda5-phosphane 以 二氯甲烷 为溶剂， 以75%的产率得到Pd(C6H4(o-Ph)N(PPh2)2)Cl2
  参考文献：
  名称：

  Complexation associated rearrangement of iminobiphosphines to diphosphinoamines

  摘要：

  The reaction of the iminobiphosphines RN=PPh2-PPh2, where R = C6H4(P-CN), C6H4(m-CN), C6H4(o-C6H5), C6F5 or C6H4(o-CF3) with one molecular equivalent of M(cod)Cl-2 (M = Pd or Pt) results in a rearrangement of the N=P-P unit to the more commonly encountered P-N-P unit, forming mono-chelating complexes of general formula M{RN(PPh2)(2)}Cl-2. The related reaction of the same range of iminobiphosphines with Pt(cod)Cl-2 (but not Pd(cod)Cl-2) in 2:1 ratio affords complexes of general formula [Pt{RN(PPh2)(2)}(2)]2Cl. All 15 complexes are isolated in moderate to high yield and they have been fully characterised by spectroscopic methods. Six complexes, viz. [M{C6H4(p-CN)N(PPh2)(2)}Cl-2], [M{C6H4(m-CN)N(PPh2)(2)}Cl-2] and [M{C6H4(o-C6H5)N(PPh2}(2)) Cl-2] (M = Pd and Pt), have been characterised in the solid state by single crystal X-ray diffraction analysis. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.058