[Co(η5-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)(η4-2,4-di-tert-butyl-1,3-diphosphacyclobutadiene)] | 164017-84-9

• 英文名称: [Co(η5-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)(η4-2,4-di-tert-butyl-1,3-diphosphacyclobutadiene)]
• CAS: 164017-84-9
• 化学式: C₂₅H₄₅CoP₄
• 分子量: 528.521
• InChiKey: REBOZPPEIXNIGV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,2-二甲基丙基次基膦 、 钴 以 neat (no solvent) 为溶剂， 生成 [Co(η5-3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl)(η4-2,4-di-tert-butyl-1,3-diphosphacyclobutadiene)] 、 [Co(η5-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)(η4-2,4-di-tert-butyl-1,3-diphosphacyclobutadiene)] 、 [Co(η4-2,4,6,8-tetra-tert-butyl-1,3,5,7-tetraphosphabarrelene)(η4-2,4-di-tert-butyl-1,3-diphosphacyclobutadiene)]
  参考文献：
  名称：

  Metal vapour synthesis of phospha-organometallic compounds via reaction of cobalt atoms with the phospha-alkyne tBuCP: synthesis and structural characterisation of the sandwich compounds [Co(η5-P3C2tBu2)(η4-P2C2tBu2)], [Co(η5-P2C3tBu3)(η4-P2C2tBu2)] and the protonated tetraphospha-barrelene complex [Co(η4-P4C4tBu4H)(η4-P2C2tBu2)], the latter as its [W(CO)5] adduct

  摘要：

  The reaction of cobalt atoms with ' BuC dropP gives the sandwich compounds [Co(eta (5)-P3C2' Bu-2)(eta (4)-P2C2' Bu-2)] and [Co(eta (5)-P2C3' Bu-3)], which have both been structurally characterised by single crystal X-ray diffraction studies. The novel P2C3' Bu-3)(eta (4)-P2C2' Bu-2)] protonated tetraphospha-barrelene complex [Co(eta (P4C4)-P-4' Bu4H)(eta (4)-(P2C2Bu2)-Bu-')] is also formed in the reaction and has been structurally characterised as its [W(CO)(5)] adduct. Variable temperature NMR spectra of these complexes are reported and discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01110-x