chloro[N,N-bis(ethyl-2-thiolato)-2-(ethylthio)-ethylamine]oxorhenium(V) | 226545-14-8

• 英文名称: chloro[N,N-bis(ethyl-2-thiolato)-2-(ethylthio)-ethylamine]oxorhenium(V)
• CAS: 226545-14-8
• 化学式: C₈H₁₇ClNOReS₃
• 分子量: 461.087
• InChiKey: QXOVFKHYLDIEBY-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [ReOCl₃(PPh₃)₂] 、 N,N-bis(2-mercaptoethyl)-2-(ethylthio)ethylamine 在 NaO₂CCH₃ 作用下， 以 甲醇 为溶剂， 以35%的产率得到chloro[N,N-bis(ethyl-2-thiolato)-2-(ethylthio)-ethylamine]oxorhenium(V)
  参考文献：
  名称：

  Structural studies of ReO(V) mixed ligand [SNS][Cl] and [SNS][S] complexes

  摘要：

  The synthesis, characterization and spectroscopic properties of four oxorhenium complexes, ReO[C2H5SCH2CH2N(CH2CH2S)(2)]Cl (1), ReO[C2H5SCH2CH2N(CH2CH2S)(2)][p-CH3OC6H4S] (2), ReO[(C2H5)(2)NCH2CH2N(CH2CH2S)(2)][p-CH3C6H4S] (3), and ReO[C5H10NCH2CH2N(CH2C(CH3)(2)S)(2)][C6H5CH2S] (4) are reported. These neutral and lipophilic complexes are designed according to the '3 + 1' mixed ligand concept. X-ray crystallographic studies show that the coordination geometry around rhenium is distorted trigonal bipyramidal in complexes 2 and 3 and trigonally distorted square pyramidal in complex 4 (C15H24NO2S4Re (2), triclirzic P (1) over bar, a=9.610(2), b=9.628(2), c=11.791(2) Angstrom, alpha=108.307(8), beta=67.735(6), gamma=90.166(8)degrees, V = 950.04 Angstrom(3), Z = 2; C17H29N2OS3Re (3), monoclinic P2(t)/c, a = 13.188(1), b = 7.542(1), c = 21.193(1) Angstrom, beta = 103.260(2)degrees, V = 2051.74 Angstrom(3), Z = 4; C22H37N2OS3Re . 0.5C(2)H(5)OH (4), monoclinic P2(t)/c, a = 16.720(6), b = 11.013(3), c = 16.747(5) Angstrom, beta = 113.44(1)degrees, V = 2829.08 Angstrom(3), Z = 4. Complete assignments of H-1 and C-13 NMR resonances were made for all complexes and compared to those of analogous technetium complexes. Complex 3 was also prepared at the tracer Re-186 level. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00422-8