[Ru(B(pyrazol-1-yl)4(3,5-dimethyl-pyrazol-1-ylH)2(H2O)](OTs)*CH3OH | 878496-17-4

• 英文名称: [Ru(B(pyrazol-1-yl)4(3,5-dimethyl-pyrazol-1-ylH)2(H2O)](OTs)*CH3OH
• 英文别名: [Ru(B(pz)4)(3,5-Me2pzH)2(H2O)](OTs)*CH3OH
• CAS: 878496-17-4
• 化学式: CH₄O*C₇H₇O₃S*C₂₂H₃₀BN₁₂ORu
• 分子量: 793.68
• InChiKey: MQAVTEBCWMFETD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三(3,5-二甲基-1-吡唑基)硼氢化钾 以 二氯甲烷 、 苯 为溶剂， 生成 [Ru(B(pyrazol-1-yl)4(3,5-dimethyl-pyrazol-1-ylH)2(H2O)](OTs)*CH3OH
  参考文献：
  名称：

  Syntheses and characterization of new (pyrazolato)(pyrazole) rutheniums with κ3-polypyrazolylborates: Halogeno-anion binding through the tris(pyrazole) moiety

  摘要：

  (Polypyrazolylborato)(benzonitrile) ruthenium(II) complexes [RuCl{BR(pz)(3)}(PhCN)(2)] (R = pz, H; pz = pyrazol-1-yl), prepared from trans-[RuCl2(PhCN)(4)] and K[BR(pz)(3)], were allowed to react with potassium 3,5-dimethyl-substituted polypyrazolylborate salt K[BH(3,5-Me(2)pz)(3)], and gave (pyrazolato)(pyrazole) species of [Ru{BR(pz)(3)) (3,5-Me(2)pz)(3,5-Me(2)pzH)(2)] [R = pz (1), H (2)}, respectively. Upon protonation with HBF4 (Et2O), the species 1 was converted to a fairly stable tris(pyrazole) derivative [Ru{B(pz)(4)}(3,5-Me(2)pzH)(3)]BF4 (3), which worked as a novel halogeno-anion receptor. Moreover, the complex [RuCl2(PhCN)(4)] was treated with K[BH(3,5-Me-2-4-BrPZ)(3)] in the presence of 3,5-dimethyl-4-bromopyrazole, 3,5-Me-2-4-BrpzH, to afford [Ru{BH(3,5-Me-2-4-Brpz)(3)}(3,5-Me-2-4-Brpz)(3,5-Me2-4-BrpzH)(2)] and [Ru{BH(3,5-Me-2-4-Brpz)(3)}(3,5-Me-2-4-Brpz)(3,5-Me-2-4-BrpzH)(PhCN)]. Single-crystal X-ray structural analyses were carried out for 1, 3 center dot CHCl3, [Ru[B(pz)(4)}(3,5-Me(2)PzH)(2)(OH2)]O3SC6H4CH3 center dot CH3OH, and [RuCl{B(pz)(4))(3,5-Me(2)pzH)(2)]center dot CHCl3. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.08.005