Cu2Cl2(N,N'-dibenzyl-pyrrole-2,5-dicarbothioamide)2 | 1292297-02-9

• 英文名称: Cu2Cl2(N,N'-dibenzyl-pyrrole-2,5-dicarbothioamide)2
• CAS: 1292297-02-9
• 化学式: C₄₀H₃₆Cl₂Cu₂N₆S₄
• 分子量: 927.028
• InChiKey: WDEMGWZZFGUGCE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-dibenzyl-1H-pyrrole-2,5-dicarbothioamide 、 copper(II) choride dihydrate 以 乙醇 为溶剂， 以98%的产率得到Cu2Cl2(N,N'-dibenzyl-pyrrole-2,5-dicarbothioamide)2
  参考文献：
  名称：

  Versatile bridging ability of secondary thioamide group for constructing metal cluster based on pincer complex

  摘要：

  The crystallization of the SCS pincer platinum complex with secondary thioamide groups, [4-methyl-2,6-bis(anilinothiocarbonyl)-kappa S-2,S'-phenyl-kappa C-1]chloroplatinum(II), spontaneously forms a trinuclear cluster complex accompanied by liberating HCl in DMSO/EtOH mixture. The crystal structure of the SNS pincer copper complex with secondary thioamide groups, [2,5-bis(benzylaminothiocarbonyl)-kappa S-2,S'-pyrrolyl-kappa N-1] chlorocopper(II), exhibits a dimer structure bearing the bridging thioamide group. The thioamide group acts as the bridging ligand of the multimetallic complexes in different anionic and neutral manners. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.11.028