cis-dichloro((1,3,5,7-tetramethyl-2,4,8-trioxa-6-phosphaadamantan-6-yl)OPPh2)palladium(II) | 1310573-64-8

• 英文名称: cis-dichloro((1,3,5,7-tetramethyl-2,4,8-trioxa-6-phosphaadamantan-6-yl)OPPh2)palladium(II)
• CAS: 1310573-64-8
• 化学式: C₂₃H₂₈Cl₂O₄P₂Pd
• 分子量: 607.746
• InChiKey: SPAUNBBSPCWUDV-ZFAXIJQASA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (1,3,5,7-tetramethyl-2,4,8-trioxa-6-phosphaadamantan-6-yl)methanol 、 dichloro(cycloocta-1,5-diene)palladium (II) 、 二苯基氯化膦 以 二氯甲烷 为溶剂， 以91%的产率得到cis-dichloro((1,3,5,7-tetramethyl-2,4,8-trioxa-6-phosphaadamantan-6-yl)OPPh2)palladium(II)
  参考文献：
  名称：

  Metal(II) template assisted syntheses of two P―C―O―P chelating ligands incorporating a bulky 1,3,5,7-tetramethyl-2,4,8-trioxa-6-phosphaadamantyl cage

  摘要：

  Facile condensation of one equiv. of the caged hydroxymethylphosphine Ad'PCH(2)OH (Ad' = C(10)H(16)O(3)) with ClPR(2) (R = Ph, (i)Pr), in the presence of one equiv. of MCl(2)(cod) (M = Pt, Pd; cod = cycloocta-1,5-diene), afforded the five-membered chelate complexes cis-MCl(2)(Ad'PCH(2)OPR(2)) (la, M = Pt, R = Ph; 1b, M = Pd, R = Ph; 2a, M = Pt, R = (i)Pr) in reasonable to excellent yields. The X-ray structures of la and 2a have been determined, the latter using diffraction data collected at a synchrotron source. The M-P-C-O-P metallacycle remains intact even after stirring in CD(3)OD for 24 h at room temperature. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.03.037