Os3(CO)10(η4-1,5-cyclooctadiene) | 716371-45-8

• 英文名称: Os3(CO)10(η4-1,5-cyclooctadiene)
• 英文别名: Os3(CO)10(η4-1,5-COD)
• CAS: 716371-45-8
• 化学式: C₁₈H₁₂O₁₀Os₃
• 分子量: 958.887
• InChiKey: PNFRVCAILVFCDH-HINHTODJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Os3(CO)10(η4-1,5-cyclooctadiene) 以 正己烷 为溶剂， 以88%的产率得到(μ-H)Os3(CO)9(μ,η4-C8H11)
  参考文献：
  名称：

  Complexation and C–H bond activation of 1,5-cyclooctadiene on triosmium carbonyl clusters

  摘要：

  Reaction of Os-3(CO)(10)(NCMe)(2) and 1,5-cyclooctadiene (C8H12) affords the diene complex Os-3(CO)(10)(eta(4)-C8H12) (1) with the two alkene moieties coordinated to an equatorial and an axial positions of one osmium atom. Thermolysis of I in refluxing n-hexane results in a vinylic C-H bond activation to form (mu-H)Os-3(CO)(9)(mu, n(4)-C8H11) (2) in good isolated yield. The crystal structures of 1 and 2 have been established by an X-ray diffraction study, (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.018
• 作为产物：
  描述：

  bis(acetonitrile)decacarbonyltriosmium 、 1,5-环辛二烯 以 二氯甲烷 为溶剂， 以71%的产率得到Os3(CO)10(η4-1,5-cyclooctadiene)
  参考文献：
  名称：

  Complexation and C–H bond activation of 1,5-cyclooctadiene on triosmium carbonyl clusters

  摘要：

  Reaction of Os-3(CO)(10)(NCMe)(2) and 1,5-cyclooctadiene (C8H12) affords the diene complex Os-3(CO)(10)(eta(4)-C8H12) (1) with the two alkene moieties coordinated to an equatorial and an axial positions of one osmium atom. Thermolysis of I in refluxing n-hexane results in a vinylic C-H bond activation to form (mu-H)Os-3(CO)(9)(mu, n(4)-C8H11) (2) in good isolated yield. The crystal structures of 1 and 2 have been established by an X-ray diffraction study, (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.03.018