[Ru(5-bromo-1,3-di(1-n-butyl-1,2,3-triazol-4-yl)benzene(-1H))(2,2':6',2''-terpyridine)]PF6 | 1285707-32-5

• 英文名称: [Ru(5-bromo-1,3-di(1-n-butyl-1,2,3-triazol-4-yl)benzene(-1H))(2,2':6',2''-terpyridine)]PF6
• CAS: 1285707-32-5
• 化学式: C₃₃H₃₃BrN₉Ru*F₆P
• 分子量: 881.623
• InChiKey: HOMBDGKNLDUVAB-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  N-溴代丁二酰亚胺(NBS) 、 [Ru(1,3-di(1-n-butyl-1,2,3-triazol-4-yl)benzene(-1H))(2,2':6',2''-terpyridine)]PF6*H2O 以 乙腈 为溶剂， 以63%的产率得到[Ru(5-bromo-1,3-di(1-n-butyl-1,2,3-triazol-4-yl)benzene(-1H))(2,2':6',2''-terpyridine)]PF6
  参考文献：
  名称：

  Tridentate Cyclometalated Ruthenium(II) Complexes of “Click” Ligand 1,3-Di(1,2,3-triazol-4-yl)benzene

  摘要：

  A tridentate cyclometalating ligand, 1,3-di(1,2,3-triazol-4-yl)benzene (dtab), has been prepared and used for the syntheses of a number of cyclometalated Ru-II complexes. A comparison of the electrochemical and spectroscopic properties of cyclometalated complexes made from dtab or 1,3-di(2-pyridyl)benzene is presented as well.

  DOI：

  10.1021/om200039j