catena-poly[[tetrakis(2-allyltetrazole-κN4)-tetra-μ-chloro-tricopper(II)]-di-μ-chloro] | 564473-20-7

• 英文名称: catena-poly[[tetrakis(2-allyltetrazole-κN4)-tetra-μ-chloro-tricopper(II)]-di-μ-chloro]
• CAS: 564473-20-7
• 化学式: C₁₆H₂₄Cl₆Cu₃N₁₆
• 分子量: 843.83
• InChiKey: JMELUFXVMJLOOJ-UHFFFAOYSA-H

反应信息

• 作为产物：
  描述：

  poly[[dichlorocopper(II)]-di-μ2-2-allyl-2H-tetrazole-κ2N1:N4] 以 异丙醇 、 正丁醇 为溶剂， 生成 catena-poly[[tetrakis(2-allyltetrazole-κN4)-tetra-μ-chloro-tricopper(II)]-di-μ-chloro]
  参考文献：
  名称：

  catena-Poly[[tetrakis(2-allyltetrazole-κN⁴)-tetra-μ-chloro-tricopper(II)]-di-μ-chloro]

  摘要：

  In the crystal structure of the title compound, [Cu3Cl6-(C4H6N4)(4)](n), there are three Cu atoms, six Cl atoms and four 2-allyltetrazole ligands in the asymmetric unit. The polyhedron of one Cu atom adopts a flattened octahedral geometry, with two 2-allyltetrazole ligands in the axial positions [Cu-N4=1.990 (2) and 1.991 (2) Angstrom] and four Cl atoms in the equatorial positions [Cu-Cl=2.4331 (9)-2.5426 (9) Angstrom]. The polyhedra of the other two Cu atoms have a square-pyramidal geometry, with three basal sites occupied by Cl atoms [Cu-Cl=2.2487 (9)-2.3163 (8) and 2.2569 (9)-2.3034 (9) Angstrom] and one basal site occupied by a 2-allyltetrazole ligand [Cu-N4 =2.028(2) and 2.013 (2) Angstrom]. A Cl atom lies in the apical position of either pyramid [Cu-Cl=2.8360 (10) and 2.8046 (9) Angstrom]. The possibility of including the tetrazole N3 atoms in the coordination sphere of the two Cu atoms is discussed. Neighbouring copper polyhedra share their edges with Cl atoms to form one-dimensional polymeric chains running along the a axis.

  DOI：

  10.1107/s0108270103002968