[(η5-C5H5)Fe(η5-C5H4)C(CH3)N]2(C6H4) | 945654-92-2

• 英文名称: [(η5-C5H5)Fe(η5-C5H4)C(CH3)N]2(C6H4)
• CAS: 945654-92-2
• 化学式: C₃₀H₂₈Fe₂N₂
• 分子量: 528.26
• InChiKey: FTMYRFKOVSEUDS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η5-C5H5)Fe(η5-C5H4)C(CH3)N]2(C6H4) 、 mercury(II) diacetate 、 lithium chloride 以 not given 为溶剂， 以40%的产率得到[(η5-C5H5)Fe(η5-C5H3(mercury)Cl)C(CH3)N]2(C6H4)
  参考文献：
  名称：

  Synthesis and Crystal Structure of Bis(cyclomercurated) Bisferrocenylimines

  摘要：

  The new complexes of bis(cyclomercurated) bisferrocenylimines were synthesised in good yields by the cyclomercuration of Schiff bases bearing acylferrocene and p-phenylenediamine at room temperature. All the new compounds' identities were completely elucidated by various spectroscopic methods. The X-ray crystal structure confirmed that the mercury was directed into the ortho-position of substituted Cp ring and showed the presence of two N --> Hg coordinations via two 5-membered rings in these molecules.

  DOI：

  10.1080/15533170600862218
• 作为产物：
  描述：

  乙酰基二茂铁 、 对苯二胺 在 Al₂O₃ 作用下， 以 甲苯 为溶剂， 生成 [(η5-C5H5)Fe(η5-C5H4)C(CH3)N]2(C6H4)
  参考文献：
  名称：

  Synthesis and Crystal Structure of Bis(cyclomercurated) Bisferrocenylimines

  摘要：

  The new complexes of bis(cyclomercurated) bisferrocenylimines were synthesised in good yields by the cyclomercuration of Schiff bases bearing acylferrocene and p-phenylenediamine at room temperature. All the new compounds' identities were completely elucidated by various spectroscopic methods. The X-ray crystal structure confirmed that the mercury was directed into the ortho-position of substituted Cp ring and showed the presence of two N --> Hg coordinations via two 5-membered rings in these molecules.

  DOI：

  10.1080/15533170600862218