| 327597-05-7

• CAS: 327597-05-7
• 化学式: C₆H₅O*C₃₁H₆₉OP₄Pd₂
• 分子量: 887.728
• InChiKey: ZLXFEGDBERVIJK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-Di(propan-2-yl)phosphanylpropyl-di(propan-2-yl)phosphane;palladium;tricyclohexylphosphane 以 氘代甲苯 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, Characterization, and Reactivity of [((ⁱPr)₂P(CH₂)₃P(ⁱPr)₂)(PCy₃)PdH][OR]

  摘要：

  The preparation of (DIPPP)Pd(PR3) and [(DIPPP)(PR3)PdH][OR'] (DIPPP = bis(1,3-diisopropylphosphino)propane; R = Cy, Et; R' = Ar, CF3SO2) is reported. (DIPPP)Pd(PCy3) and [(DIPPP)(PCy3)PdH][CF3SO3] have been structurally characterized. (DIPPP)Pd(PR3) complexes catalyze the reaction of ethylene with carbon monoxide and phenols to give aryl propionates. In situ P-31 NMR experiments have shown that the resting state of the catalyst in these transformations is the binuclear species [C(DIPPP)Pd)(2)(mu -H)(mu -CO)][OPh].

  DOI：

  10.1021/om0008833