[1-(3-ammoniumpropyl)silatrane]1-(3-carbamatepropyl)silatrane | 1356961-61-9

• 英文名称: [1-(3-ammoniumpropyl)silatrane]1-(3-carbamatepropyl)silatrane
• CAS: 1356961-61-9
• 化学式: C₉H₂₀N₂O₃Si*C₁₀H₂₀N₂O₅Si
• 分子量: 508.72
• InChiKey: IRHDUXWYCCUQCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三乙醇胺 、 硅烷偶联剂 KH-540 在 sodium 作用下， 反应 2.0h， 以83.9%的产率得到[1-(3-ammoniumpropyl)silatrane]1-(3-carbamatepropyl)silatrane
  参考文献：
  名称：

  Synthesis and structural characterization of 1-(3-aminopropyl)silatrane and some new derivatives

  摘要：

  The research goal was to synthesize and structurally characterize a silatrane intended to be subsequently incorporated into metal complex structures. 3-Aminopropyltrialkoxysilane was reacted with triethanolamine in 1:1 molar ratio, either in bulk, in the presence of metallic sodium, or in a solvent mixture. 1-(3-Aminopropyl)silatrane in carbamate form or having free amine groups was obtained. The latter was reacted with 2-hydroxybenzaldehyde, 2,4-dihydroxybenzaldehyde and CoCl2 or with CoCl2 only. The crystalline reaction products were characterized by elemental and spectral (FTIR and H-1 NMR) analyses and single crystal X-ray diffractometry, which revealed the formation of new, either sought (1-(3-aminopropyl)silatrane, 1-(3-salicyliminopropyl)silatrane) or unexpected (N-carboxylated 1-(3-aminopropyl)silatrane and 1-chlorocobaltrane) structures. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.11.014