[Pt(7,8-benzoquinolinato)(1,2-bis(diphenylphosphino)ethane)]PF6 | 198885-63-1

• 英文名称: [Pt(7,8-benzoquinolinato)(1,2-bis(diphenylphosphino)ethane)]PF6
• CAS: 198885-63-1
• 化学式: C₃₉H₃₂NP₂Pt*F₆P
• 分子量: 916.681
• InChiKey: VOSFOZYRKPKUPJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 7,8-苯并喹啉 、 [platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] 在 AgNO₃ 作用下， 以 二氯甲烷 为溶剂， 以16%的产率得到[Pt(7,8-benzoquinolinato)(1,2-bis(diphenylphosphino)ethane)]PF6
  参考文献：
  名称：

  Structure, physical and photophysical properties of platinum(II) complexes containing 7,8-benzoquinoline and various bis(diphenylphosphine) ligands

  摘要：

  A series of platinum complexes, [Pt(7,8-bzq)(dppm)](PF6), [Pt(7,8-bzq)(dppe)](PF6) and [Pt(7,8-bzy)(dppp)](PF6), which vary only in the number of carbon atoms bridging two diphenyl phosphine ligands, have been synthesized and their structures have been determined by single crystal X-ray crystallography. Structural characteristics are as follows: [Pt(7,8-bzq)(dppm)](PF6), orthorhombic, Pbca, a = 17.427(4), b = 17.946(4), c = 22.262 Angstrom, Z = 8; [Pt(7,8-bzq)(dppe)](PF6), monoclinic, P2(1)/c, a = 11.519(2), b = 14.080(3), c = 21.804(4) Angstrom, Z = 4; [Pt(7,8-bzq)(dppp)](PFepsilon), Pna2(1), a = 20.216(4), b = 11.574(2), c = 15.739(3) Angstrom, Z = 4. The P-Pt-P bite angle varies in the series from 72.1(5) to 84.5(2) to 91.57(10)degrees for [Pt(7,8-bzq)(dppm)](+), [Pt(7,8-bzq)(dppe)](+) and [Pt(7,8-bzq)(dppp)](+), respectively. The absorption spectra are blue-shifted and the emission lifetimes at 77 K increase in the same order. Emission lifetime differences are shown to relate to the perturbation associated with the additional methylene groups. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05688-0