[Ir(μ-S(CH2)3NMe2)(CO)2]2 | 166897-59-2

• 英文名称: [Ir(μ-S(CH2)3NMe2)(CO)2]2
• CAS: 166897-59-2
• 化学式: C₁₄H₂₄Ir₂N₂O₄S₂
• 分子量: 732.928
• InChiKey: RYJROBPZYQTBFM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3-(二甲基氨基)-1-丙硫醇 在 CO 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 生成 [Ir(μ-S(CH2)3NMe2)(CO)2]2
  参考文献：
  名称：

  Preparation, structure and reactivity of dinuclear aminothiolate-bridged iridium complexes

  摘要：

  Addition of the aminothiolate HS(CH2)(3)NMe(2) and potassium tert-butoxide to [{Ir(mu-Cl)(cod)}(2)] (cod = cycloocta-1,5-diene) afforded the aminothiolate-bridged complex [{Ir[mu-S(CH2)(3)NMe(2)]-(cod)}(2)] 1. This reacted with carbon monoxide to give the dinuclear tetracarbonyl complex [{Ir[mu-(CH2)(3)NMe(2)](CO)(2)}(2)] 2. The reaction of 1 with CO and phosphines or of 2 with phosphines provided the mixed-ligand complexes trans-[{Ir[mu-S(CH2)(3)NMe(2)](CO)(PR(3))}(2)] (R = C6H11 3, o-MeC(6)H(4) 4 or p-FC6H4 5). When the bulky phosphite P(OC(6)H(4)Bu(t)-o)(3) was used as phosphorus ligand the orthometallated complex trans-[{Ir[mu-S(CH2)(3)NMe(2)]H(CO)[P(OC(6)H(3)Bu(t)-o)(OC(6)H(4)Bu(t)-o)(2)]}(2)] 6 was obtained. The crystal structures of 1 and 6, have been determined by X-ray diffraction methods.

  DOI：

  10.1039/dt9950002137