| 476629-66-0

• CAS: 476629-66-0
• 化学式: C₂₅H₂₄Cl₂NPPd
• 分子量: 546.772
• InChiKey: TWEBEOJFUBVTJP-XNLHTSAWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 2,6-二甲基苯基异腈 以 二氯甲烷 为溶剂， 以88%的产率得到(8-((2,6-dimethylphenyl)imino)-1-phenyl-3,3a,8,8a-tetrahydro-1l5-indeno[2,1-b]phosphol-1(2H)-yl)(((2,6-dimethylphenyl)imino)methyl)palladium(IV) chloride
  参考文献：
  名称：

  Iminophosphine Palladium Complexes in Catalytic Stille Coupling Reactions:  From Monomers to Dendrimers

  摘要：

  Palladium complexes of a variety of beta- and gamma-iminophosphines have been prepared and characterized by X-ray diffraction studies. Their properties as catalyst for three different Stille coupling reactions have been investigated and compared to catalytic performances of a phosphorus-containing dendrimer incorporating analogous gamma-iminophosphine palladium complexes on the surface.

  DOI：

  10.1021/om011076m
• 作为产物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 N-(2,6-dimethylphenyl)-3-phenyl-1,2,3a,8b-tetrahydroindeno[2,1-b]phosphol-4-imine 以 二氯甲烷 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Iminophosphine Palladium Complexes in Catalytic Stille Coupling Reactions:  From Monomers to Dendrimers

  摘要：

  Palladium complexes of a variety of beta- and gamma-iminophosphines have been prepared and characterized by X-ray diffraction studies. Their properties as catalyst for three different Stille coupling reactions have been investigated and compared to catalytic performances of a phosphorus-containing dendrimer incorporating analogous gamma-iminophosphine palladium complexes on the surface.

  DOI：

  10.1021/om011076m