MoCl4(methyldiphenylphosphine oxide)2 | 517863-77-3

• 英文名称: MoCl4(methyldiphenylphosphine oxide)2
• CAS: 517863-77-3
• 化学式: C₂₆H₂₆Cl₄MoO₂P₂
• 分子量: 670.191
• InChiKey: WHKUDQNLNIGGMO-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrachlorobis(tetrahydrofurano)molybdenum(IV) 、 甲基二苯基氧化膦 以 苯 为溶剂， 以65%的产率得到MoCl4(methyldiphenylphosphine oxide)2
  参考文献：
  名称：

  Packing and compositional disorder with MoO2Cl2(OPMePh2)2, MoOCl3(OPMePh2)2 and MoCl4(OPMePh2)2 as assessed by single crystal X-ray diffraction

  摘要：

  The structures as determined by single crystal X-ray determinations Of MoO2Cl2(OPMePh2)(2) and various mixtures of MoO2Cl2(OPMePh2)(2) (A), MoOCl3(OPMePh2)(2) (B) and MoCl4(OPMePh2)(2) (C) specifically in ratios 40.2/59.8; 30.8/69.2; 14/86; 4/96 in A/B, 100% B and 82/18 in B/C are reported. The structural data illustrate that both compositional and packing disorder afford mechanisms by which apparent long and different Mo-O bond distances can be obtained. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01157-x