| 1415656-46-0

• CAS: 1415656-46-0
• 化学式: C₂₈H₄₀Br₂N₄Pd
• 分子量: 698.88
• InChiKey: WLZBIGCAQAEJGK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1-butyl-3-propylbenzimidazolium bromide 、 palladium diacetate 以 乙腈 为溶剂， 反应 12.0h， 以85%的产率得到
  参考文献：
  名称：

  Benzimidazole-based palladium–N-heterocyclic carbene: a useful catalyst for C–C cross-coupling reaction at ambient condition

  摘要：

  A convenient way for the synthesis of benzimidazole-based Pd-N-heterocyclic carbene complex and its structural characterization are described. The complex efficiently catalyzes Suzuki cross-coupling reaction in a wide variety of substrates including heteroaromatic system at ambient condition. The catalyst is also effective for multi Suzuki cross-coupling reaction. In addition, the catalyst is equally active toward C-C cross-coupling reaction between acid chloride and arylboronic acid, giving the desired ketones in high yield. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.10.055