[PtI2(2,9-dimethyl-1,10-phenanthroline)((C5Me4CH2CH2CH=CH2)Ir(Me)(CO)(Ph))] | 852943-99-8

• 英文名称: [PtI2(2,9-dimethyl-1,10-phenanthroline)((C5Me4CH2CH2CH=CH2)Ir(Me)(CO)(Ph))]
• CAS: 852943-99-8
• 化学式: C₃₅H₃₉I₂IrN₂OPt
• 分子量: 1144.82
• InChiKey: UKYXWYHAGNOMAP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ((allylmetyl)tetramethylcyclopentadienyl)(carbonyl)(methyl)(phenyl)iridium 、 PtI2(2,9-dimethyl-1,10-phenanthroline) 以 氯仿 为溶剂， 以90%的产率得到[PtI2(2,9-dimethyl-1,10-phenanthroline)((C5Me4CH2CH2CH=CH2)Ir(Me)(CO)(Ph))]
  参考文献：
  名称：

  Olefin uptake as tool for linking platinum(II) and iridium(III) in heterobinuclear complexes: Synthesis and characterization of [PtI2(Me2phen){(C5Me4CH2CH2CHCH2)Ir(Me)(CO)(Ph)}]

  摘要：

  The ability of [PtX2(Me(2)phen)] (Me(2)phen = 2,9-dimethyl-1,10-phenanthroline, X = Cl, Br, I) to act as olefin scavengers, easily giving stable trigonal bipyramidal five-coordinated platinum species [PtX2(Me(2)phen)(eta(2)-olefin)], has been checked toward [(C5Me4CH2CH2CH=CH2)Ir(Me)(CO)(Ph)], a cyclopentadienyl complex containing an olefinic function introduced by ring methyl activation in the pentamethylcyclopentadienyl iridium(III) complex [(C5Me5)Ir(Me)(CO)(Ph)]. The reaction of [PtI2(Me(2)phen)] with [(C5Me4CH2CH2CH=CH2)Ir(Me)(CO)(Ph)] results in the formation of the heterometallic binuclear complex [PtI2(Me(2)phen){(C5Me4CH2CH2CH=CH2)Ir(Me)(CO)(Ph)}] which is stable and has been completely characterized by elemental analysis, H-1, C-13, and Pt-195 NMR spectroscopy. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.01.003