dibromo(2-hydroxyimino-1-methylethylidene)benzhydrazideaquacobalt monohydrate | 465538-50-5

• 英文名称: dibromo(2-hydroxyimino-1-methylethylidene)benzhydrazideaquacobalt monohydrate
• CAS: 465538-50-5
• 化学式: C₁₀H₁₃Br₂CoN₃O₃*H₂O
• 分子量: 460.048
• InChiKey: INBVJIHLPYDJRG-FDYWDBDWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cobalt(II) bromide hexahydrate 、 苯甲酰肼 、 2-氧代丙醛-1-肟 以 乙醇 为溶剂， 以86%的产率得到dibromo(2-hydroxyimino-1-methylethylidene)benzhydrazideaquacobalt monohydrate
  参考文献：
  名称：

  摘要：

  Benzoylhydrazine and isonitrosoacetone react in ethanol with cobalt, nickel, and copper halides and acetates to give the coordination compounds MX2(HL) . nH(2)O, MX2(HL)(2) . nH(2)O, and ML2 . nH(2)O [M = Col Ni, Cu; X = Cl, Br; HL = C6H5C(O)NHNC(CH3)CHNOH; n = 1-4]. The same reactions pet-formed in the presence of sodium acetate and pyridine (pH 7-8) yield the complexes MLCl . nH(2)O and MPy2LCl . nH(2)O (n = 1-4). All the complexes have a pseudooctahedral coordination geometry. The hydrazone HL behaves as a tridentate O,N,N-donor ligand. Thermolysis of the substances involves dehydration (70-90degreesC), deaquation (155-170degreesC) or deamination (175-195degreesC), and complete thermal decomposition (285-360degreesC).

  DOI：

  10.1023/a:1015490022087