[(pentamethylcyclopentadiene)(PMe₃)IrH(TFA)] | 1434170-01-0

• 英文名称: [(pentamethylcyclopentadiene)(PMe₃)IrH(TFA)]
• CAS: 1434170-01-0
• 化学式: C₁₅H₂₅F₃IrO₂P
• 分子量: 517.551
• InChiKey: UNMBQXHMXGHDPP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (C5Me5)(PMe3)Ir(p-C6H4CH3)(H) 、 [(1,5-cyclooctadiene)Pt(Me)(trifluoroacetate)] 以 氘代苯 为溶剂， 以13%的产率得到[(pentamethylcyclopentadiene)(PMe₃)IrH(TFA)]
  参考文献：
  名称：

  Transmetalation of Alkyl Ligands from Cp*(PMe₃)IrR¹R²to (cod)PtR³X

  摘要：

  Transmetalation of alkyl and carboxylate ligands between Cp*(PMe3)Ir complexes and d(8) Pt and Pd complexes is described. Studies on the scope and kinetics of this reaction support a mechanism in which carboxylate dissociation from the Pt or Pd center precedes alkyl transfer from Ir. Subsequent reaction of the resulting Pt or Pd alkyl complex enables functionalization of the hydrocarbyl ligands and suggests new opportunities for catalytic, nondirected C-C and C-H bond functionalization reactions.

  DOI：

  10.1021/om400289s