[tricarbonyl(η(6)-4-chloroanisole)manganese]BF4 | 166543-63-1

• 英文名称: [tricarbonyl(η(6)-4-chloroanisole)manganese]BF4
• 英文别名: [(4-MeOC6H4Cl)Mn(CO)3]BF4；[(η6-1-chloro-4-methoxybenzene)Mn(CO)3][BF4]；[(η6-1-chloro-4-methoxybenzene)Mn(CO)3]BF4；[(η5-para-chloroanisole)Mn(CO)3]BF4
• CAS: 166543-63-1
• 化学式: BF₄*C₁₀H₇ClMnO₄
• 分子量: 368.359
• InChiKey: FVBGRLTZVLPNHL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四(三苯基膦)钯 、 [tricarbonyl(η(6)-4-chloroanisole)manganese]BF4 以 甲苯 为溶剂， 以99%的产率得到cis-[(Pd(PPh3)2Cl)(4-MeOC6H4)(Mn(CO)3)]BF4
  参考文献：
  名称：

  Oxidative addition of cationic (η6-chloroarene)tricarbonylmanganese compounds to palladium(0) complexes. Synthesis, characterisation and reactivity

  摘要：

  The oxidative addition of the coordinated chloroarene in [(4-RC(6)H(4)Cl)Mn(CO)(3)][X] (R = H, OCH3; X = PF6, BF4) to [Pd(PPh(3))(4)] proceeds readily at room temperature to give [{eta(6)-[{PdCl(PPh(3))(2)}(4-RC(6)H(4))(Mn(CO)(3)][X]. P-31{H-1} NMR analysis of these square-planar palladium complexes revealed that the phosphorus ligands are cis. In contrast to their tricarbonylchromium analogues, these manganese complexes could not be carbonylated because the electron-withdrawing effect of the Mn(CO)(3)(+) moiety is too strong.

  DOI：

  10.1016/0022-328x(95)05472-2
• 作为产物：
  描述：

  五羰基溴化锰(I) 、 4-氯苯甲醚 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以70%的产率得到[tricarbonyl(η(6)-4-chloroanisole)manganese]BF4
  参考文献：
  名称：

  Balssa, Frederic; Gagliardini, Vanessa; Rose-Munch, Francoise, Organometallics, 1996, vol. 15, p. 4373 - 4382

  摘要：

  DOI：

文献信息

• Synthesis and Reactivity of (η⁵-Hydroxyalkylcyclohexadienyl)Mn(CO)₃ Complexes
  作者：Derya Cetiner、Lucie Norel、Jean-Philippe Tranchier、Françoise Rose-Munch、Eric Rose、Patrick Herson

  DOI：10.1021/om100062m

  日期：2010.4.12

  hexadienyl)tricarbonylmanganese complexes 3a and 3b have been prepared, and their rearomatization delivered compounds 5 and 6, the first benzylic alcohol derivatives coordinated to the cationic Mn(CO)3 tripod. The structure of 5 has been determined by X-ray crystallography. 1-Hydroxyalkyl 3a, 7, 8, 2-hydroxyalkyl 19, 20, and 3-hydroxyalkyl 25, 26 (η5-cyclohexadienyl)tricarbonylmanganese complexes have

  （η 5 -1- Hydroxyalkylcyclohexadienyl）tricarbonylmanganese络合物图3a和3b中已经制备，以及它们的rearomatization递送化合物5和6，配位到该阳离子的Mn（CO）第一苄醇衍生物3的三脚架。5的结构已经通过X射线晶体学确定。1-羟3A，7，8，2-羟烷基19，20，和3-羟基25，26（η 5-环己二烯基）三羰基锰配合物已经合成并研究了在NEt 3和（CF 3 CO）2 O的作用下对羟基的三氟乙酰化作用。只有2-羟烷基取代的配合物因其Mn-CO键而黯然失色。 Mn（CO）3三脚架给出了预期的三氟乙酸酯衍生物21和22。对于1-羟基烷基取代的配合物，消除三氟乙酰氧基的发生，接着将Mn（CO）的decoordination 3部分和三氟乙酰化，从而产生trifluoromethyltrienones 10，11，和12，其结构是
• New access to (η5-cyclohexadienyl)Mn(CO)3 and cationic (η6-arene)Mn(CO)3 complexes by Suzuki–Miyaura reaction
  作者：Françoise Rose-Munch、Alex Marti、Derya Cetiner、Jean-Philippe Tranchier、Eric Rose

  DOI：10.1039/c0dt01270j

  日期：——

  First Suzuki–Miyaura coupling reactions applied to (η5-chloro-cyclohexadienyl)Mn(CO)3 complexes are described and lead to the syntheses of (η5-aryl-cyclohexadienyl)Mn(CO)3 and of cationic (η6-arene)Mn(CO)3 complexes after rearomatization. The structures of two of the new complexes have been investigated by X-ray diffraction study.

  第一铃木-宫浦偶联反应应用到（η 5 -氯环己二烯基）锰（CO）3个配合物被描述和导致的合成（η 5 -芳基-环己二烯基）锰（CO）3和阳离子（η 6 -芳构化后的芳烃）Mn（CO）3配合物。X射线衍射研究已经研究了两种新配合物的结构。
• η⁶-(Arene)tricarbonylchromium and Manganese Complexes Linked to 2‘-Deoxyuridine
  作者：Mélanie Etheve-Quelquejeu、Jean-Philippe Tranchier、Françoise Rose-Munch、Eric Rose、Lieve Naesens、Erik De Clercq

  DOI：10.1021/om700674v

  日期：2007.11.1

  Synthesis of η6-(arene)tricarbonylchromium and manganese complexes linked to 2‘-deoxyuridine via a triple-bond spacer is reported using palladium-catalyzed reactions of alkynes with halogeno derivatives, and their antiviral activity in cell-based assays studied.

  η的合成6 - （芳烃）tricarbonylchromium并经由三键间隔使用炔烃的钯催化的反应与卤代衍生物被报告链接到-2'-脱氧尿苷锰配合物，并在基于细胞的测定它们的抗病毒活性的研究。
• Synthesis, Characterization, and PGSE (¹H and ¹⁹F) NMR Diffusion Studies on Cationic (η⁶- Arene)Mn(CO)₃⁺ Complexes:  Boron Counterion, Ion Pairing, and Solvent Dependences
  作者：Daniele Schott、Paul S. Pregosin、Béatrice Jacques、Murielle Chavarot、Françoise Rose-Munch、Eric Rose

  DOI：10.1021/ic0506409

  日期：2005.8.1

  The synthesis, characterization, and PGSE (H-1 and F-19) NMR diffusion studies on the cationic [(eta(6)-arene)Mn-(CO)(3)][X] (arene = anisole, 4-chloroanisole, and 1,3,5-trimethoxybenzene; X = BPh4 and BArF) are reported. The tetraphenyl borate complexes of anisole and 4-chloroanisole show surprisingly strong ion pairing in dichloromethane solution, whereas the BArF salts do not. H-1,H-1-NOESY data support this anion selectivity. In chloroform solution one finds the usual strong ion pairing for both anions. The solid-state structure of [(eta(6)-1,3,5-trimethoxybenzene)-Mn(CO)(3)][BPh4] has been determined. C-13 NMR and IR data for the new complexes are reported. The observed IR frequencies are higher for the BArF complexes than for the BPh4 complexes.
• Reactivity of Keto-Substituted (η⁵-Cyclohexadienyl)Mn(CO)₃ Complexes toward Hydrides
  作者：Antoine Eloi、Françoise Rose-Munch、Dayana Jonathan、Jean-Philippe Tranchier、Eric Rose

  DOI：10.1021/om050956o

  日期：2006.9.1

  Reaction of hydrides with (eta(5)-ketocyclohexadienyl) Mn(CO)(3) complexes yielded the corresponding alcohols as major products but also cyclohexadienes due to the addition of hydride to the C-2 carbon of the C-1-C-5 pi-system. This unexpected regioselectivity has been established by different labeling experiments. The structures of one of the starting keto-substituted (eta(5)-cyclohexadienyl) Mn(CO)(3) complexes and its corresponding alcohol have been determined by X-ray crystallography.