[2-(1-acetyl-5-(2-hydroxyphenyl)-4-phenyl-1,2,4-diazaphospholan-3-yl)phenyl acetate-κP]chloro(η4-cycloocta-1,5-diene)rhodium(I) | 546126-40-3

• 英文名称: [2-(1-acetyl-5-(2-hydroxyphenyl)-4-phenyl-1,2,4-diazaphospholan-3-yl)phenyl acetate-κP]chloro(η4-cycloocta-1,5-diene)rhodium(I)
• CAS: 546126-40-3
• 化学式: C₃₂H₃₅ClN₂O₄PRh
• 分子量: 680.973
• InChiKey: KLKUPOWIXVYVFL-VPEBZQEHSA-M

反应信息

• 作为产物：
  描述：

  chloro(1,5-cyclooctadiene)rhodium(I) dimer 、 (1-acetyl-5-(2-hydroxyphenyl)-4-phenyl-1,2,4-diazaphospholan-3-yl)phenyl acetate 以 二氯甲烷 为溶剂， 以99%的产率得到[2-(1-acetyl-5-(2-hydroxyphenyl)-4-phenyl-1,2,4-diazaphospholan-3-yl)phenyl acetate-κP]chloro(η4-cycloocta-1,5-diene)rhodium(I)
  参考文献：
  名称：

  A 1,2,4-diazaphospholane complex of rhodium

  摘要：

  The crystal structure of a prospective olefin catalyst, namely {2-[1-acetyl-5-(2-hydroxyphenyl)-4-phenyl-1,2,4-diazaphospholan-3-yl]phenyl acetate-kappaP}chloro(eta(4)-cycloocta-1,5-diene)rhodium(I) dichloromethane solvate, [RhCl(C8H12)(C24H23N2O4P)].CH2Cl2, has been determined at 173 K. The five-membered heterocycle of the phosphine ligand is in a slightly distorted twist conformation. An intramolecular N1-H1...Cl1 hydrogen bond contributes to the adopted conformation and may additionally participate in secondary interactions with substrates during catalysis.

  DOI：

  10.1107/s0108270103002142