| 159574-65-9

• CAS: 159574-65-9；159574-64-8；159542-85-5
• 化学式: C₆H₁₆Cl₂PtSe₄
• 分子量: 670.019
• InChiKey: IAAQUCOBVKIPJO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 [(Pt(MeSeCH2SeMe)Cl2)n]
  参考文献：
  名称：

  Synthesis and spectroscopic studies of palladium and platinum complexes of methylene-backboned dithio-, diseleno- and ditelluro-ether ligands, RECH2ER (R = Me or Ph; E = S, Se or Te)

  摘要：

  The complexes [ML2Cl2] (M = Pd or Pt; L = PhSCH2SPh, MeSCHSMe, PhSeCH2SePh or MeSeCH2SeMe), which are square planar with monodentate sulfur or selenium ligands, have been prepared. In the solid state, on the basis of IR and Raman data, the palladium complexes are trans and the platinum cis, whilst in solution multinuclear NMR spectroscopy (H-1, Pt-195-{H-1}, and Se-77-{H-1}) reveal that both cis and trans isomers and meso and DL enantiomers are present, the isomer populations varying with L and M in a systematic way. The complexes [MLCl2] are stable in solution for L = PhSCH2SPh, but the other complexes lose L to precipitate polymeric [(MLCl2)n] complexes. The ditelluroethers, MeTeCH2TeMe and PhTeCH2TePh, form only the latter type of complex. The crystal structure of trans-[Pd(PhSCH2SPh)2Cl2] has been determined and contains a trans square-planar palladium atom with one co-ordinated and one free sulfur atom associated with each dithioether ligand [Pd-Cl 2.292(l) and Pd-S 2.329(l) angstrom].

  DOI：

  10.1039/dt9940002835
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 bis(methylselanyl)methane 以 乙醇 、 二氯甲烷 、 水 为溶剂， 生成 、 [(Pt(MeSeCH2SeMe)Cl2)n]
  参考文献：
  名称：

  Synthesis and spectroscopic studies of palladium and platinum complexes of methylene-backboned dithio-, diseleno- and ditelluro-ether ligands, RECH2ER (R = Me or Ph; E = S, Se or Te)

  摘要：

  The complexes [ML2Cl2] (M = Pd or Pt; L = PhSCH2SPh, MeSCHSMe, PhSeCH2SePh or MeSeCH2SeMe), which are square planar with monodentate sulfur or selenium ligands, have been prepared. In the solid state, on the basis of IR and Raman data, the palladium complexes are trans and the platinum cis, whilst in solution multinuclear NMR spectroscopy (H-1, Pt-195-{H-1}, and Se-77-{H-1}) reveal that both cis and trans isomers and meso and DL enantiomers are present, the isomer populations varying with L and M in a systematic way. The complexes [MLCl2] are stable in solution for L = PhSCH2SPh, but the other complexes lose L to precipitate polymeric [(MLCl2)n] complexes. The ditelluroethers, MeTeCH2TeMe and PhTeCH2TePh, form only the latter type of complex. The crystal structure of trans-[Pd(PhSCH2SPh)2Cl2] has been determined and contains a trans square-planar palladium atom with one co-ordinated and one free sulfur atom associated with each dithioether ligand [Pd-Cl 2.292(l) and Pd-S 2.329(l) angstrom].

  DOI：

  10.1039/dt9940002835