[iridium(I)(1,5-cyclooctadiene)(1,10-phenanthroline)](BF4) dihydrate | 89436-90-8

• 英文名称: [iridium(I)(1,5-cyclooctadiene)(1,10-phenanthroline)](BF4) dihydrate
• 英文别名: [Ir(cod)(phen)](BF4)*2H2O；[Ir(cyclooctadiene)(1,10-phenanthroline)]BF4
• CAS: 89436-90-8
• 化学式: BF₄*C₂₀H₂₀IrN₂
• 分子量: 567.417
• InChiKey: YYNBEGCPBSGPGJ-ONEVTFJLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrafluoroboric acid 、 [Ir(acetylacetonate-C(3))(cyclooctadiene)(1,10-phenanthroline)] 以 乙醚 为溶剂， 以55%的产率得到[iridium(I)(1,5-cyclooctadiene)(1,10-phenanthroline)](BF4) dihydrate
  参考文献：
  名称：

  Synthesis and crystal structure of [Ir(acac-C3)(COD)(phen)]

  摘要：

  DOI：

  10.1016/s0022-328x(00)99281-7

文献信息

• Properties and biological activity of [Rh(COD)(N–N)]BF4 and [IrCl2(COD)(N–N)]BF4 polypyridyl complexes
  作者：Urszula Śliwińska-Hill、Florian P. Pruchnik、Małgorzata Latocha、Dominika Nawrocka-Musiał、Stanisław Ułaszewski

  DOI：10.1016/j.ica.2013.02.002

  日期：2013.5

  Square planar rhodium(I) complexes [Rh(COD)(N-N)]BF4 (COD = 1,5-cyclooctadiene, N-N = 1,10-phenanthroline (phen) (1), 2,2'-bipyridine (bpy) (2), 4,7-diphenyl-1,10-phenanthroline (dpphen)(3), 4,4'-dimethyl-2,2'-bipyridine (dmbpy) (4), dipyrido[3,2-a:2',3'-c]-phenazine (dppz) (5), 2,9-dimethyl-1,10-phenanthroline (dmphen)(6)) and octahedral iridium(III) complexes [IrCl2(COD)(N-N)]BF4 (COD = 1,5-cyclooctadiene, N-N = 1,10-phenanthroline (phen)(7), 2,2'-bipyridine (bpy) (8), 4,4'-dimethyl-2,2'-bipyridine (dmbpy) (9)) have been obtained and characterized using spectroscopic methods. They are active agents towards Caco-2, Sk-mel, SNB-19 and C-32 tumor cells. Complexes 3, 5 and 6 are also efficient antibacterial agents against Gram-positive bacteria and compound 3 shows antifungal activity against AD1-9 and FY yeast strains. (C) 2013 Elsevier B.V. All rights reserved.