[dirhenium(III)-cis-tetrachloro-di-(μ-adamantanecarboxylate)] | 541539-48-4

• 英文名称: [dirhenium(III)-cis-tetrachloro-di-(μ-adamantanecarboxylate)]
• 英文别名: cis-[Re2(AdCOO)2Cl4]
• CAS: 541539-48-4
• 化学式: C₂₂H₃₀Cl₄O₄Re₂
• 分子量: 872.704
• InChiKey: HBSMUIAFXRLMKL-YYKUZNBSSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [dirhenium(III)-cis-tetrachloro-di-(μ-adamantanecarboxylate)] 、 乙腈 以 乙腈 为溶剂， 生成 [dirhenium(III)-cis-tetrachloro-di-(μ-adamantanecarboxylate)(acetonitrile)2]
  参考文献：
  名称：

  Cluster rhenium(III) complexes with adamantanecarboxylic acids: Synthesis and properties

  摘要：

  Versatile procedures for the synthesis of possible structural types of dirhenium(III) halocarboxylates with adamantanecarboxylic acids were developed. A comprehensive study of the synthesis and interconversions of isomeric dirhenium(III) trans- and cis-tetrahalodi-mu-carboxylates led us to a discovery of a versatile route of prepation of trans derivatives in virtually stoichiometric yields in both the solid and liquid phases. It was found that successive replacement of halide ligands in the nearest environment of the binuclear Re-2(6+) ion by carboxylate ligands is accompanied by gradual hypsochromic shifting of the longest-wavelength absorption band and by a monotonic decline in its intensity, which allows this band to be assigned to the delta-delta* electronic transition.

  DOI：

  10.1134/s1070328406040038
• 作为产物：
  描述：

  [dirhenium(III)-cis-tetrachloro-di-(μ-adamantanecarboxylate)(water)2] 以 neat (no solvent) 为溶剂， 生成 [dirhenium(III)-cis-tetrachloro-di-(μ-adamantanecarboxylate)]
  参考文献：
  名称：

  Cluster rhenium(III) complexes with adamantanecarboxylic acids: Synthesis and properties

  摘要：

  Versatile procedures for the synthesis of possible structural types of dirhenium(III) halocarboxylates with adamantanecarboxylic acids were developed. A comprehensive study of the synthesis and interconversions of isomeric dirhenium(III) trans- and cis-tetrahalodi-mu-carboxylates led us to a discovery of a versatile route of prepation of trans derivatives in virtually stoichiometric yields in both the solid and liquid phases. It was found that successive replacement of halide ligands in the nearest environment of the binuclear Re-2(6+) ion by carboxylate ligands is accompanied by gradual hypsochromic shifting of the longest-wavelength absorption band and by a monotonic decline in its intensity, which allows this band to be assigned to the delta-delta* electronic transition.

  DOI：

  10.1134/s1070328406040038