trans-bis[1,1,1-tricarbonyl-5-methyl-aza(5)-μ-oxa(2)-rhena(1)-cyclopentane] | 618885-08-8

• 英文名称: trans-bis[1,1,1-tricarbonyl-5-methyl-aza(5)-μ-oxa(2)-rhena(1)-cyclopentane]
• CAS: 618885-08-8
• 化学式: C₁₂H₁₆N₂O₈Re₂
• 分子量: 688.682
• InChiKey: LJLDSUAFDFPURI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  N-甲基-2-羟基乙胺 、 (OC)4Re(η(3)-C3H5) 以 正辛烷 为溶剂， 以98%的产率得到trans-bis[1,1,1-tricarbonyl-5-methyl-aza(5)-μ-oxa(2)-rhena(1)-cyclopentane]
  参考文献：
  名称：

  Synthesis of the dimeric, N substituted μ2-O aminoalkoxy complexes of rhenium [(CO)3Re(μ2-O∩NHR)]2

  摘要：

  The allyl rhenium complex Re(CO)(4)(eta(3)-C3H5) (1) reacts with the N substituted amino alcohols 2a-f to give the N substituted dimeric mu2-O-bridged tricyclic aminoalkoxy complexes of rhenium of the type [(CO)(3)Re(mu(2)-(ONHR)-N-boolean AND)](2) (3a-f). The compounds have been characterized by spectroscopic (IR, NMR, NIS), analytical (C, H, N) and X-ray diffraction techniques (3a-f). (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1387-7003(03)00119-9