[(Cu2L(Phe))Cl4] | 599212-09-6

• 英文名称: [(Cu2L(Phe))Cl4]
• CAS: 599212-09-6
• 化学式: C₁₅H₂₄Cl₄Cu₂N₄O
• 分子量: 545.286
• InChiKey: NLGQPQSHJMTHFD-RCZOLUBLSA-J

反应信息

• 作为产物：
  描述：

  2-amino-3-phenyl-1-(1,4,7-triazonan-1-yl)propan-1-one 、 copper dichloride 以 甲醇 为溶剂， 以50%的产率得到[(Cu2L(Phe))Cl4]
  参考文献：
  名称：

  TACN−Amino Acid Conjugates and Their Copper(II) Complexes

  摘要：

  Triazacyclononane (TACN) was coupled to glycine (L-Gly), alanine (L-Ala), and phenylalanine (L-Phe) via standard solution phase peptide coupling techniques. Copper(II) complexes of these new ligand-amino acid conjugates' [(CuLGly)(2)](ClO4)(4) (1), [(CuLAla)(2)Cl](ClO4)(3) (2), and [(Cu2LCl4)-Cl-Phe] (3), were synthesized and characterized. The X-ray crystal structures of 2 and 3 were determined. Complex 2 is a dimeric species where, L-Ala bridges between copper ions via its two TACN amine nitrogen atoms to one copper while the Ala terminal amine and carbonyl oxygen bind to the other copper. Complex 3 is bimetallic but only contains one L-Phe ligand that bridges between the copper ions.

  DOI：

  10.1021/ic034598y